The Development of Polydimethysiloxane/ZnO–GO Antifouling Coatings

Abstract

The development of antifouling coating for sensor is desirable because the biofilm can shorten sensor’s life and cause inaccurate reading. In this study, a facile one-pot reaction was used to synthesized ZnO–graphene oxide (GO) (ZnO–GO) nanocomposites. Different amount of ZnO–GO was incorporated in the polydimethylsiloxane (PDMS) matrix respectively though a simple solution mixing method, in order to create PDMS/ZnO–GO nanocomposite (PZGO). The coating was obtained directly by spin coating of PZGO/tetrahydrofuran suspension. The hydrophobicity, surface roughness (Ra), surface free-energy (SFE) and nanoscale structure were investigated as antifouling factors. Antifouling tests were performed using two marine microorganisms, the cyanobacterium Synechococcus sp. Strain PCC 7002 and the diatom Phaeodactylum tricornutum. PZGO0.2 (mass ratio of ZnO–GO to PDMS: 0.2 wt%) displayed excellent antifouling property with 8.5% of Synechococcus sp. Strain PCC 7002 biofilm coverage, while PZGO0.1 (mass ratio of ZnO–GO to PDMS: 0.1 wt%) showed 2.4% P. tricornutum biofilm coverage. The antifouling property of the synthesized PZGO nanocomposite can be attributed to its high Ra and hydrophobicity which was caused by the good dispersion of ZnO–GO in PDMS matrix. This study suggests a potential of PZGO nanocomposite for sensor’s antifouling coating, which could contribute to improve sensor’s durability relating to biofouling in future.