Synthesis of magnesium complexes of ionic liquids with highly coordinating anion
dc.contributor.author | Kallidanthiyil Chellappan, Lethesh | |
dc.contributor.author | Fiksdahl, Anne | |
dc.contributor.author | Jayasayee, Kaushik | |
dc.contributor.author | Øien-Ødegaard, Sigurd | |
dc.date.accessioned | 2019-09-16T06:17:16Z | |
dc.date.available | 2019-09-16T06:17:16Z | |
dc.date.created | 2019-01-14T09:03:21Z | |
dc.date.issued | 2019 | |
dc.identifier.issn | 1477-9226 | |
dc.identifier.uri | http://hdl.handle.net/11250/2616851 | |
dc.description.abstract | Magnesium(II) complexes, [Mg2+(hfac−)3][Cation+], were prepared as solids from hydrophobic hexafluoroacetylacetonate ionic liquids ([Cation+][hfac−] ILs) and Mg(Tf2N)2. 1-Butyl-3-methylimidazolium ([C4mim]), N-butylpyridinium ([C4Pyr]), N-butyl-N-methylpiperidinium ([C4Pip]), N-hexyl-N-methylmorpholinium ([C6Morp]) and N-butyl-N-methylpyrrolidinium ([C4pyrr]) were used as cationic cores. The [C4Pip][hfac], [C4Pyr][hfac] and [C6Morp][hfac] ILs were prepared for the first time. New Mg(II) complexes, [C4mim][Mg(hfac)3], [C4Pip][Mg(hfac)3], [C4Pyr][Mg(hfac)3], [C6Morp][Mg(hfac)3] and [C4Pyrr][Mg(hfac)3], were obtained from the [hfac] based ILs. The crystal structures of the novel Mg(II) complexes show the coordination of three [hfac] anions to the Mg2+ ion through the two oxygen atoms of each [hfac] anion. | nb_NO |
dc.language.iso | eng | nb_NO |
dc.publisher | Royal Society of Chemistry | nb_NO |
dc.title | Synthesis of magnesium complexes of ionic liquids with highly coordinating anion | nb_NO |
dc.type | Journal article | nb_NO |
dc.type | Peer reviewed | nb_NO |
dc.description.version | publishedVersion | nb_NO |
dc.source.volume | 3 | nb_NO |
dc.source.journal | Dalton Transactions | nb_NO |
dc.identifier.doi | 10.1039/C8DT04364G | |
dc.identifier.cristin | 1655804 | |
dc.description.localcode | This article will not be available due to copyright restrictions (c) 2018 by Royal Society of Chemistry | nb_NO |
cristin.unitcode | 194,66,25,0 | |
cristin.unitname | Institutt for kjemi | |
cristin.ispublished | false | |
cristin.fulltext | original | |
cristin.qualitycode | 1 |
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