dc.contributor.author | Liao, Jinyun | |
dc.contributor.author | Feng, Yufa | |
dc.contributor.author | Lin, Weimin | |
dc.contributor.author | Su, Xinlong | |
dc.contributor.author | Ji, Shan | |
dc.contributor.author | Li, Liling | |
dc.contributor.author | Zhang, Wanling | |
dc.contributor.author | Pollet, Bruno | |
dc.contributor.author | Li, Hao | |
dc.date.accessioned | 2021-04-21T10:45:31Z | |
dc.date.available | 2021-04-21T10:45:31Z | |
dc.date.created | 2020-03-12T06:49:04Z | |
dc.date.issued | 2020 | |
dc.identifier.citation | International Journal of Hydrogen Energy. 2020, 45 (15), 8168-8176. | en_US |
dc.identifier.issn | 0360-3199 | |
dc.identifier.uri | https://hdl.handle.net/11250/2738849 | |
dc.description.abstract | Dehydrogenation of hydrogen-rich chemicals, such as ammonia borane (AB), is a promising way to produce hydrogen for mobile fuel cell power systems. However, the practical application has been impeded due to the high cost and scarcity of the catalysts. Herein, a low-cost and high-performing core-shell structured CuO–NiO/Co3O4 hybrid nanoplate catalytic material has been developed for the hydrolysis of AB. The obtained hybrid catalyst exhibits a high catalytic activity towards the hydrolysis of AB with a turnover frequency (TOF) of 79.1 molH2 mol cat−1 min−1. The apparent activation energy of AB hydrolysis on CuO–NiO/Co3O4 is calculated to be 23.7 kJ.mol−1. The synergistic effect between CuO–NiO and Co3O4 plays an important role in the improvement of the catalytic performance. The development of this high-performing and low-cost CuO–NiO/Co3O4 hybrid catalytic material can make practical applications of AB hydrolysis at large-scale possible. | en_US |
dc.language.iso | eng | en_US |
dc.publisher | Elsevier Science | en_US |
dc.rights | Attribution-NonCommercial-NoDerivatives 4.0 Internasjonal | * |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/4.0/deed.no | * |
dc.title | CuO–NiO/Co3O4 hybrid nanoplates as highly active catalyst for ammonia borane hydrolysis | en_US |
dc.type | Peer reviewed | en_US |
dc.type | Journal article | en_US |
dc.description.version | acceptedVersion | en_US |
dc.source.pagenumber | 8168-8176 | en_US |
dc.source.volume | 45 | en_US |
dc.source.journal | International Journal of Hydrogen Energy | en_US |
dc.source.issue | 15 | en_US |
dc.identifier.doi | 10.1016/j.ijhydene.2020.01.155 | |
dc.identifier.cristin | 1801247 | |
dc.description.localcode | © 2020. This is the authors’ accepted and refereed manuscript to the article. Locked until 13 February 2022 due to copyright restrictions. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/ | en_US |
cristin.ispublished | true | |
cristin.fulltext | preprint | |
cristin.qualitycode | 1 | |