dc.contributor.author | Wang, Lu | |
dc.contributor.author | Shao, Yuanlong | |
dc.contributor.author | Jiang, Bo | |
dc.contributor.author | Fiksdahl, Anne | |
dc.contributor.author | Jayasayee, Kaushik | |
dc.date.accessioned | 2021-02-24T12:55:30Z | |
dc.date.available | 2021-02-24T12:55:30Z | |
dc.date.created | 2020-01-06T13:50:52Z | |
dc.date.issued | 2019 | |
dc.identifier.citation | ACS Applied Materials & Interfaces. 2019, 11 (41), 37595-37601. | en_US |
dc.identifier.issn | 1944-8244 | |
dc.identifier.uri | https://hdl.handle.net/11250/2730126 | |
dc.description.abstract | The development of Mg batteries based on the interfacial charge storage mechanism, where the capacity originates from capacitive processes and the solvent-related interfacial reactions, could efficiently circumvent the challenge of intercalation-based Mg batteries with sluggish kinetics. In this work, the proposed Mg organohaloaluminate mixture electrolyte is reported to improve the charge storage performance of the graphene-supported cathodes, resulting in both high cycling stability (91% capacity retention after 2000 cycles) and high rate capability (51% capacity retention when the current density increases by 100 times). The experimental and computational studies have revealed that the exceptional cell performance originates from the optimized electrode/electrolyte interface, where the highly reversible interfacial reactions occur with the 1,2-dimethoxyethane additive in the typical all-phenyl complex electrolyte. The fast charge-transfer kinetics along the surface of highly porous and conductive graphene-supported electrodes have also been observed. | en_US |
dc.language.iso | eng | en_US |
dc.publisher | American Chemical Society | en_US |
dc.relation.uri | https://pubs.acs.org/doi/10.1021/acsami.9b11215 | |
dc.title | Rational design of mixed solvent and porous graphene-supported spinel oxide electrodes for high-rate and long cycle-life Mg batteries | en_US |
dc.type | Peer reviewed | en_US |
dc.type | Journal article | en_US |
dc.description.version | publishedVersion | en_US |
dc.source.pagenumber | 37595-37601 | en_US |
dc.source.volume | 11 | en_US |
dc.source.journal | ACS Applied Materials & Interfaces | en_US |
dc.source.issue | 41 | en_US |
dc.identifier.doi | 10.1021/acsami.9b11215 | |
dc.identifier.cristin | 1766900 | |
dc.relation.project | Norges forskningsråd: 255108 | en_US |
dc.relation.project | Norges forskningsråd: NN9264K | en_US |
dc.description.localcode | This article will not be available due to copyright restrictions (c) 2019 by ACS | en_US |
cristin.ispublished | true | |
cristin.fulltext | original | |
cristin.qualitycode | 1 | |