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Studies on gold-nitrone systems

Jonsson, Helgi Freyr; Fiksdahl, Anne
Journal article, Peer reviewed
Published version
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Jonsson (Locked)
URI
http://hdl.handle.net/11250/2616850
Date
2019
Metadata
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  • Institutt for kjemi [805]
  • Publikasjoner fra CRIStin - NTNU [20804]
Original version
Dalton Transactions. 2019, 48 142-149.   10.1039/c8dt04254c
Abstract
Novel Au(I)​-​nitrone complexes with specific catalytic properties were prepd. Also, Au(I)​- and Au(III)​-​oxadiazole complexes were formed by a novel Au-​generated nitrile-​nitrone [3 + 2] cycloaddn., and the crystal structures of Au(I)​-​nitrones as well as the Au(I)​- and Au(III)​-​oxadiazole complexes were studied (x-​ray)​. A useful 1-​pot Au(III)​-​mediated cycloaddn. method was developed for the formation of a no. of dihydro-​1,​2,​4-​oxadiazoles, involving in situ formation of Au(III)​-​oxadiazole complexes. The obsd. Au(I) and Au(III) dual selective reactivity gives new understanding about the Au(I)​- and Au(III)​-​nitrone chemistry
Publisher
Royal Society of Chemistry
Journal
Dalton Transactions

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