dc.contributor.author | Tsakoumis, Nikolaos | |
dc.contributor.author | Johnsen, Rune E. | |
dc.contributor.author | van Beek, Wouter | |
dc.contributor.author | Rønning, Magnus | |
dc.contributor.author | Rytter, Erling | |
dc.contributor.author | Holmen, Anders | |
dc.date.accessioned | 2017-10-10T07:52:55Z | |
dc.date.available | 2017-10-10T07:52:55Z | |
dc.date.created | 2016-07-20T09:29:43Z | |
dc.date.issued | 2016 | |
dc.identifier.citation | Chemical Communications. 2016, 52 (15), 3239-3242. | nb_NO |
dc.identifier.issn | 1359-7345 | |
dc.identifier.uri | http://hdl.handle.net/11250/2459327 | |
dc.description.abstract | The reduction of a Re promoted Co/γ-Al2O3 catalyst was monitored in situ by synchrotron X-ray powder diffraction (XRPD) under H2 environment. Whole powder pattern analysis revealed a non-linear expansion of the unit cell of γ-Al2O3 during the reduction process, suggesting the diffusion of Co cations into the structure of the support. The non-linear cell expansion coincided with the formation of a CoO phase. In addition, space resolved diffraction at the inlet and the outlet of the reactor evidenced a negative effect of the partial pressure of indigenous H2O(g) on the reduction process. | nb_NO |
dc.language.iso | eng | nb_NO |
dc.publisher | Royal Society of Chemistry | nb_NO |
dc.title | Capturing metal-support interactions in situ during the reduction of a Re promoted Co/γ-Al2O3 catalyst | nb_NO |
dc.type | Journal article | nb_NO |
dc.type | Peer reviewed | nb_NO |
dc.description.version | acceptedVersion | nb_NO |
dc.source.pagenumber | 3239-3242 | nb_NO |
dc.source.volume | 52 | nb_NO |
dc.source.journal | Chemical Communications | nb_NO |
dc.source.issue | 15 | nb_NO |
dc.identifier.doi | 10.1039/c5cc09879c | |
dc.identifier.cristin | 1368665 | |
dc.description.localcode | © The Royal Society of Chemistry 2016. This is the authors accepted and refereed manuscript to the article. | nb_NO |
cristin.unitcode | 194,66,30,0 | |
cristin.unitname | Institutt for kjemisk prosessteknologi | |
cristin.ispublished | true | |
cristin.fulltext | postprint | |
cristin.qualitycode | 1 | |