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dc.contributor.authorRamos Wanderley, Ricardo
dc.contributor.authorHøisæter, Karen Karolina
dc.contributor.authorKnuutila, Hanna K
dc.date.accessioned2023-12-11T10:02:28Z
dc.date.available2023-12-11T10:02:28Z
dc.date.created2021-12-14T10:43:00Z
dc.date.issued2021
dc.identifier.issn1750-5836
dc.identifier.urihttps://hdl.handle.net/11250/3106800
dc.description.abstractWater-lean solvents are solvents for CO2 capture which contain at least one amine and one organic diluent. Carbamate-forming amines in nonaqueous water-lean solvents typically absorb CO2 through the formation of carbamate species. Conversely, tertiary amines in nonaqueous amino-organic mixtures cannot form carbamate nor undergo bicarbonate formation. However, protic organic diluents might take part in an alkylcarbonate formation pathway: in this route, the diluent is deprotonated by the amine, and its conjugate base is then able to react directly with CO2 to form an alkylcarbonate. This is an interesting reaction mechanism, as it offers a possibility for formulating solvents that deviate from the two most common reaction pathways for CO2 absorption (i.e., carbamate and bicarbonate formation). The present study introduces a simple way for evaluating alkylcarbonate-forming water-lean solvents based on the properties of its single constituents, namely the basicity of the amine and the autoprotolysis constant of the organic diluent. Our theoretical framework shows that higher CO2 absorption capacities can be obtained for solvents containing amines with high pKa and diluents with low pKs. We assess both the challenges and possibilities for alkylcarbonate-forming solvents and propose a framework for their development and utilization in the industry.en_US
dc.language.isoengen_US
dc.publisherElsevier B. V.en_US
dc.rightsNavngivelse 4.0 Internasjonal*
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/deed.no*
dc.titleSigns of alkylcarbonate formation in water-lean solvents: VLE-based understanding of pKa and pKs effectsen_US
dc.title.alternativeSigns of alkylcarbonate formation in water-lean solvents: VLE-based understanding of pKa and pKs effectsen_US
dc.typePeer revieweden_US
dc.typeJournal articleen_US
dc.description.versionpublishedVersionen_US
dc.source.volume109en_US
dc.source.journalInternational Journal of Greenhouse Gas Controlen_US
dc.identifier.doi10.1016/j.ijggc.2021.103398
dc.identifier.cristin1968133
dc.source.articlenumber103398en_US
cristin.ispublishedtrue
cristin.fulltextoriginal
cristin.qualitycode1


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