dc.contributor.author | Wagner, Nils Peter | |
dc.contributor.author | Dalod, Antoine Robert Marie | |
dc.contributor.author | Svensson, Ann Mari | |
dc.contributor.author | Vullum-Bruer, Fride | |
dc.date.accessioned | 2017-10-30T14:35:54Z | |
dc.date.available | 2017-10-30T14:35:54Z | |
dc.date.created | 2015-08-11T08:09:15Z | |
dc.date.issued | 2015 | |
dc.identifier.citation | ECS Transactions. 2015, 64 (22), 33-45. | nb_NO |
dc.identifier.issn | 1938-5862 | |
dc.identifier.uri | http://hdl.handle.net/11250/2462946 | |
dc.description.abstract | Lithium transition-metal silicate materials are promising candidates for next generation Li-ion batteries since they allow Li extraction/insertion beyond one Li ion per formula unit. They consist of cheap, non-toxic and abundant elements. Here we focus on the synthesis and electrochemical performance of Fe and V substituted Li2MnSiO4. Cations were substituted to overcome poor stability of the undoped compound and increase conductivity, thus expected to increase the electrochemical performance. Up to 20 mole % Fe and 5 mole % V were incorporated into orthorhombic Pmn21 Li2MnSiO4 while keeping a high phase purity and the desired porous nano-sized structure. For materials with 20 mole % Fe substitution, the reversible Li intercalation capacity during slow cycling (C/33) was increased from 0.63 Li per formula unit for the undoped to 0.81 for the doped sample. A 5 mole % V substitution increased the reversible Li capacity from 0.65 Li per formula unit to 0.73. | nb_NO |
dc.language.iso | eng | nb_NO |
dc.publisher | Electrochemical Society | nb_NO |
dc.title | Fe and V substituted Li2MnSiO4/C As Potential Cathode Material for Li-Ion Batteries | nb_NO |
dc.type | Journal article | nb_NO |
dc.type | Peer reviewed | nb_NO |
dc.description.version | acceptedVersion | nb_NO |
dc.source.pagenumber | 33-45 | nb_NO |
dc.source.volume | 64 | nb_NO |
dc.source.journal | ECS Transactions | nb_NO |
dc.source.issue | 22 | nb_NO |
dc.identifier.doi | 10.1149/06422.0033ecst | |
dc.identifier.cristin | 1257190 | |
dc.relation.project | Norges forskningsråd: 216469 | nb_NO |
dc.description.localcode | © 2015 ECS - The Electrochemical Society. This is the authors' accepted and refereed manuscript to the article. | nb_NO |
cristin.unitcode | 194,66,35,0 | |
cristin.unitname | Institutt for materialteknologi | |
cristin.ispublished | true | |
cristin.fulltext | postprint | |
cristin.qualitycode | 1 | |