Crystal structure, thermal expansion and electrical conductivity of LaCoxNiyMozO3
Journal article, Peer reviewed
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Original versionDalton Transactions. 2016, 45 (39), 15290-15293. 10.1039/c6dt03265f
The effect of Mo-substitution was investigated for the LaCoxNiyMozO3 system, obtaining single-phase perovskite for Mo-substitutions up to 20 at%. The crystal structure of the perovskite changed from rhombohedral, orthorhombic to monoclinic with increasing Mo-content. The thermal expansion was suppressed by Mo-substitution, while the electrical conductivity was also suppressed, but remained relatively high.