Blar i NTNU Open på forfatter "Gavrilovic, Ljubisa"
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Deactivation of Co-Based Fischer−Tropsch Catalyst by Aerosol Deposition of Potassium Salts
Gavrilovic, Ljubisa; Brandin, Jan; Holmen, Anders; Venvik, Hilde Johnsen; Myrstad, Rune; Blekkan, Edd Anders (Journal article; Peer reviewed, 2018)A 20%Co/0.5%Re/γAl2O3 Fischer−Tropsch catalyst was poisoned by four potassium salts (KNO3, K2SO4, KCl, and K2CO3) using the aerosol deposition technique, depositing up to 3500 ppm K as solid particles. Standard characterization ... -
Effect of trace potassium on hydrogen adsorption and dissociation on hcp cobalt: A density functional theory study
Chen, Qingjun; Svenum, Ingeborg-Helene; Gavrilovic, Ljubisa; Chen, De; Blekkan, Edd Anders (Journal article; Peer reviewed, 2018)Trace amounts of potassium (K) have a significant influence on the activity and selectivity of cobalt-based catalysts in Fischer–Tropsch synthesis (FTS), in which hydrogen adsorption and dissociation is one of the initial ... -
Effects of K adsorption on the CO-induced restructuring of Co(11-20)
Strømsheim, Marie Døvre; Svenum, Ingeborg-Helene; Farstad, Mari Helene; Li, Zheshen; Gavrilovic, Ljubisa; Guo, Xiaoyang; Lervold, Stine; Borg, Anne; Venvik, Hilde Johnsen (Journal article; Peer reviewed, 2017)The location of potassium (K) on Cobalt (Co) and its effect on adsorption and adsorption-induced surface restructuring is important for understanding the deactivation of Co Fischer-Tropsch catalysts and the nature of the ... -
Fischer-Tropsch synthesis over an alumina-supported cobalt catalyst in a fixed bed reactor – Effect of process parameters
Gavrilovic, Ljubisa; Jørgensen, Erik Andreas; Pandey, Umesh; Putta, Koteswara Rao; Rout, Kumar Ranjan; Rytter, Erling; Hillestad, Magne; Blekkan, Edd Anders (Peer reviewed; Journal article, 2020)Fischer-Tropsch synthesis has been investigated over a commercial type cobalt-based catalyst (20 %Co/0.5 %Re/γ-Al2O3) by varying the H2/CO ratio (2.55–1.12), CO conversion (15–75 %), reaction temperature (210 °C, 230 °C), ... -
Fischer-Tropsch synthesis—Investigation of the deactivation of a Co catalyst by exposure to aerosol particles of potassium salt
Gavrilovic, Ljubisa; Brandin, Jan; Holmen, Anders; Venvik, Hilde Johnsen; Myrstad, Rune; Blekkan, Edd Anders (Journal article; Peer reviewed, 2018)The influence of potassium species on a Co based Fischer-Tropsch catalyst was investigated using an aerosol deposition technique. This way of poisoning the catalyst was chosen to simulate the actual potassium behaviour ... -
Modeling Fischer–Tropsch kinetics and product distribution over a cobalt catalyst
Pandey, Umesh; Runningen, Anders; Gavrilovic, Ljubisa; Jørgensen, Erik Andreas; Putta, Koteswara Rao; Rout, Kumar Ranjan; Rytter, Erling; Blekkan, Edd Anders; Hillestad, Magne (Peer reviewed; Journal article, 2021)A detailed kinetic model describing the consumption of key components and productdistribution in the Fischer–Tropsch synthesis (FTS) over a 20%Co/0.5Re γ-Al2O3commercial catalyst is developed. The developed model incorporates ... -
Optimal Renewable Energy Distribution Between Gasifier and Electrolyzer for Syngas Generation in a Power and Biomass-to-Liquid Fuel Process
Putta, Koteswara Rao; Pandey, Umesh; Gavrilovic, Ljubisa; Rout, Kumar Ranjan; Rytter, Erling; Blekkan, Edd Anders; Hillestad, Magne (Peer reviewed; Journal article, 2022)By adding energy as hydrogen to the biomass-to-liquid (BtL) process, several published studies have shown that carbon efficiency can be increased substantially. Hydrogen can be produced from renewable electrical energy ... -
Potassium adsorption behavior on hcp cobalt as model systems for the Fischer–Tropsch synthesis: a density functional theory study
Chen, Qingjun; Svenum, Ingeborg-Helene; Qi, Yanying; Gavrilovic, Ljubisa; Chen, De; Holmen, Anders; Blekkan, Edd Anders (Journal article; Peer reviewed, 2017)Potassium (K), an important impurity in syngas from biomass, can have a large influence on the activity and selectivity of cobalt-based Fischer–Tropsch synthesis (FTS) catalysts in Biomass to Liquids (BTL) processes. In ... -
Sorption-enhanced Fischer-Tropsch synthesis – Effect of water removal
Gavrilovic, Ljubisa; Kazi, Saima Sultana; Oliveira, Antonio; Encinas, Oscar Luis Ivanez; Blekkan, Edd Anders (Peer reviewed; Journal article, 2024)The Sorption-Enhanced Fischer-Tropsch synthesis (SEFTS), with water removal by means of a solid sorbent, has been demonstrated for the first time experimentally. Commercial water sorbents (Zeolites type 13X and 4 A) were ... -
The effect of aerosol-deposited ash components on a cobalt-based Fischer–Tropsch catalyst
Gavrilovic, Ljubisa; Brandin, Jan; Holmen, Anders; Venvik, Hilde Johnsen; Myrstad, Rune; Blekkan, Edd Anders (Journal article; Peer reviewed, 2019)The effect of ash salts on Co-based Fisher–Tropsch catalysts was studied using an aerosol deposition technique. The major elements in the ash were found to be K, S and Cl. The ash was deposited on a calcined catalyst as ... -
The Effect of Potassium on Cobalt-based Fischer-Tropsch Catalysts of Small and Medium Cobalt Particle Sizes
Save, Jonas (Master thesis, 2018)The effect of potassium on a 20 wt.% Co - 0.5 wt.% Re/-Al2O3 catalyst consisting of small and medium cobalt particle sizes were investigated. The particle sizes were adjusted by using different mixtures of ethylene glycol ... -
The Effect of Potassium on Cobalt-Based Fischer– Tropsch Catalysts with Different Cobalt Particle Sizes
Gavrilovic, Ljubisa; Save, Jonas; Blekkan, Edd Anders (Journal article; Peer reviewed, 2019)The effect of K on 20%Co/0.5%Re/γ-Al2O3 Fischer–Tropsch catalysts with two different cobalt particle sizes (small, in the range 6–7 nm and medium size, in the range 12–13 nm) was investigated. The catalyst with the smaller ...