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dc.contributor.authorHoseinpur Kermani, Arman
dc.contributor.authorTang, Kai
dc.contributor.authorUlyashin, Alexander
dc.contributor.authorPalitzch, Wolfram
dc.contributor.authorSafarian, Jafar
dc.date.accessioned2023-01-09T10:24:26Z
dc.date.available2023-01-09T10:24:26Z
dc.date.created2023-01-06T11:02:59Z
dc.date.issued2023
dc.identifier.issn0927-0248
dc.identifier.urihttps://hdl.handle.net/11250/3041892
dc.description.abstractConsidering the boom of Si solar cell installation, it is necessary to establish a process for recycling of Si from End-of-life photovoltaics (PVs). Silicon in the PVs is synthetically doped and coated by various elements and hence dedicated methods will be required for recycling of Si, back to the SoG-Si. In this research, recycling of Si from the shredded solar cells is studied by means of vacuum refining process. In this research the rejected solar cells after the firing step are treated by acid etching techniques to remove the Al back layer and the Ag finger on the front side of the cells, providing a product called de-metallized Si fragments. The vacuum refining experiments were carried out on demetallized Si fragments. Results showed the demetallized Si contained presence of P (11.67 ppmw), B (1 ppmw), Ca with up to 0.28 wt%, Ag (96 ppmw) and Sn (136 ppmw), while other metallic impurities were lower. We have shown that Sn, Ag, O, N, and Mg can be removed from the Si melt via short vacuum refining, while a complete removal of Ca and P required longer times compared to the mentioned impurities. Because vacuum refining process is not limited by thermodynamic equilibrium, a full removal of all the volatile impurities at extended times is expected and then this process has a high chance for returning the recovered Si to the solar grade requirements.en_US
dc.language.isoengen_US
dc.publisherElsevier Scienceen_US
dc.rightsAttribution-NonCommercial-NoDerivatives 4.0 Internasjonal*
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/deed.no*
dc.titleToward the recovery of solar silicon from end-of-life PVs by vacuum refiningen_US
dc.title.alternativeToward the recovery of solar silicon from end-of-life PVs by vacuum refiningen_US
dc.typePeer revieweden_US
dc.typeJournal articleen_US
dc.description.versionpublishedVersionen_US
dc.source.volume521en_US
dc.source.journalSolar Energy Materials and Solar Cellsen_US
dc.identifier.doi10.1016/j.solmat.2023.112181
dc.identifier.cristin2101888
cristin.ispublishedtrue
cristin.fulltextoriginal
cristin.qualitycode2


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Attribution-NonCommercial-NoDerivatives 4.0 Internasjonal
Except where otherwise noted, this item's license is described as Attribution-NonCommercial-NoDerivatives 4.0 Internasjonal