dc.contributor.author | Sørli, Guro | |
dc.contributor.author | Azim, Muhammad Mohsin | |
dc.contributor.author | Rønning, Magnus | |
dc.contributor.author | Mathisen, Karina | |
dc.date.accessioned | 2021-10-27T09:26:52Z | |
dc.date.available | 2021-10-27T09:26:52Z | |
dc.date.created | 2021-07-05T15:17:04Z | |
dc.date.issued | 2021 | |
dc.identifier.issn | 1463-9076 | |
dc.identifier.uri | https://hdl.handle.net/11250/2825928 | |
dc.description.abstract | The first successful synthesis of hierarchical CuSAPO-34 (3.9 wt% Cu) is reported using the polymer Pluronic F127 as a mesoporous structure directing agent (SDA). X-Ray absorption spectroscopy (XAS) revealed single site Cu2+ with 4 nearest oxygen neighbours at 1.96 Å. A catalytic model reaction, the selective reduction of NO with different sized hydrocarbons as reductants, explained that Cu2+ is accessible and reactive in both micro- and mesopores of the hierarchical CuSAPO-34. The presence of mesopores resulted in superior lifetime of the hierarchical CuSAPO-34 in the catalytic model reaction, selective oxidation of propene. | en_US |
dc.language.iso | eng | en_US |
dc.publisher | Royal Society of Chemistry | en_US |
dc.title | Improved lifetime and stability of copper species in hierarchical, copper-incorporated CuSAPO-34 verified by catalytic model reactions | en_US |
dc.type | Peer reviewed | en_US |
dc.type | Journal article | en_US |
dc.description.version | acceptedVersion | en_US |
dc.rights.holder | This is the authors' accepted manuscript to an article published by Royal Society of Chemistry. Locked until 5.7.2022 due to copyright restrictions. | en_US |
dc.source.journal | Physical Chemistry, Chemical Physics - PCCP | en_US |
dc.identifier.doi | 10.1039/D1CP01898A | |
dc.identifier.cristin | 1920346 | |
cristin.ispublished | true | |
cristin.fulltext | postprint | |
cristin.qualitycode | 2 | |