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dc.contributor.authorLin, Dong
dc.contributor.authorFeng, Xiang
dc.contributor.authorWu, Yining
dc.contributor.authorDing, Baodong
dc.contributor.authorLu, Teng
dc.contributor.authorLiu, Yibin
dc.contributor.authorChen, Xiaobo
dc.contributor.authorChen, De
dc.contributor.authorYang, Chaohe
dc.date.accessioned2019-04-10T07:53:54Z
dc.date.available2019-04-10T07:53:54Z
dc.date.created2018-11-22T14:22:32Z
dc.date.issued2018
dc.identifier.citationApplied Surface Science. 2018, 456 (31), 140-146.nb_NO
dc.identifier.issn0169-4332
dc.identifier.urihttp://hdl.handle.net/11250/2593953
dc.description.abstractUnderstanding the synergy between metal and zeolite for catalytic aquathermolysis harbours tremendous scientific and industrial importance. Herein, HZSM-5 is used as a model zeolite due to uniform physico-chemical structure, which is required to elucidate the intrinsic structure-performance relationship. We first devise a novel and scalable strategy to synthesize recyclable magnetic Fe3O4/HZSM-5 catalyst, which shows enhanced catalytic aquathermolysis performance compared to pure HZSM-5 catalyst. Moreover, the underlying synergy effect is then systematically elucidated by multi-techniques such as 1H NMR, HRTEM, Py-IR, NH3-TPD, SARA and EL. Importantly, it is found that the change of acidity is not the dominating reason for enhanced performance. The synergy not only favors dispersion of Fe3O4 nanoparticles on zeolite, but also effectively breaks CS bond and reduces the percentages of resin and asphaltene. Furthermore, the designed Fe3O4/zeolite catalyst effectively reduces the viscosity of heavy crude oil by 85.0%. This work sheds new light on the design of highly efficient heterogeneous catalysts for catalytic aquathermolysis.nb_NO
dc.language.isoengnb_NO
dc.publisherElseviernb_NO
dc.rightsAttribution-NonCommercial-NoDerivatives 4.0 Internasjonal*
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/deed.no*
dc.titleInsights into the synergy between recyclable magnetic Fe 3 O 4 and zeolite for catalytic aquathermolysis of heavy crude oilnb_NO
dc.typeJournal articlenb_NO
dc.typePeer reviewednb_NO
dc.description.versionacceptedVersionnb_NO
dc.source.pagenumber140-146nb_NO
dc.source.volume456nb_NO
dc.source.journalApplied Surface Sciencenb_NO
dc.source.issue31nb_NO
dc.identifier.doi10.1016/j.apsusc.2018.06.069
dc.identifier.cristin1633819
dc.description.localcode© 2018. This is the authors’ accepted and refereed manuscript to the article. Locked until 15.6.2020 due to copyright restrictions. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/nb_NO
cristin.unitcode194,66,30,0
cristin.unitnameInstitutt for kjemisk prosessteknologi
cristin.ispublishedtrue
cristin.fulltextpostprint
cristin.qualitycode1


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Attribution-NonCommercial-NoDerivatives 4.0 Internasjonal
Except where otherwise noted, this item's license is described as Attribution-NonCommercial-NoDerivatives 4.0 Internasjonal