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dc.contributor.advisorReenaas, Turid Worren
dc.contributor.advisorBrakstad, Thomas
dc.contributor.advisorKildemo, Morten
dc.contributor.authorDrøyli, Maja Bjerke
dc.date.accessioned2017-11-01T15:01:02Z
dc.date.available2017-11-01T15:01:02Z
dc.date.created2017-07-03
dc.date.issued2017
dc.identifierntnudaim:17851
dc.identifier.urihttp://hdl.handle.net/11250/2463526
dc.description.abstractAs a step towards reducing the CO2 emissions to the atmosphere, generating electricity from renewable energy resources instead of fossil fuels is a good contributor. Solar cells convert energy from sunlight directly into electricity, and they have long lifetimes and require little maintenance as they contain no mechanically moving parts. Even though efficiency has increased and prices have dropped significantly during the last decade, there are still many steps that can be made towards making solar cells even more attractive. Intermediate band solar cells (IBSCs) have a theoretical potential of being 50 % more efficient than the theoretically most efficient single band-gap solar cells, which is what is used in today s commercial cells, without any major increase in cost. Many steps are yet to be taken to develop highly efficient IBSCs, and one way to increase the speed and reduce the costs of this development is to perform simulations of the cells, which can lead to a better understanding of how the cells work and which compositions provides the most efficient cells. To simulate a solar cell, a good optical model is needed for that cell. Quantum dot (QD) IBSCs currently have no physically explainable, good optical models, and one way to create a model is by using spectroscopic ellipsometry (SE). In this thesis, InAs/(Al)GaAs QD-IBSCs are investigated using this technique. As a QD-IBSC has a relatively complex structure, different parts of this structure are studied separately to reduce the amount of unknowns in each measurement. This work looks into GaAs with varying doping, samples with two and ten layers of InAs QDs with GaAs and AlGaAs spacers, as well as full solar cell structures. Most emphasis is put into understanding the two-layer QD samples, as these are the simplest QD structures and therefore contain the least number of unknowns. Also, these samples have previously been measured using photoluminescence spectroscopy, atomic force microscopy, scanning electron microscopy and transmission electron microscopy, providing useful information for SE analysis. Different models from literature are applied in the modeling of QDs and wetting layer. The QD samples are first modeled only using bulk GaAs, oxide and surface roughness, before a macroscopic model with bulk InAs values and an effective medium approximation (EMA) is applied, and at last an oscillator model of Lorentz oscillators is tried. This thesis finds that the simple model outperforms the more detailed models, indicating that the assumptions made in the detailed models are not correct. Applying the oscillator model gives some surprising results indicating a negative contribution to the pseudo-dielectric function (PDF) of the sample although the oscillators have positive amplitude. No explanation to this has been found, and it is not known if this is caused by a bug in the software used for analysis or if it has a physical explanation. However, when combining the two detailed models by making an EMA of InAs and an oscillator model, the oscillator model contributes as expected to the PDF, outperforming the simple model for some of the measurements. Although the oscillator model showed some unexpected behaviour, it is still believed to be the model with most potential to make a good and physically explainable model for QDs.
dc.languageeng
dc.publisherNTNU
dc.subjectNanoteknologi, Nanoelektronikk
dc.titleSpectroscopic Ellipsometry of InAs/(Al)GaAs Quantum Dots for Intermediate Band Solar Cells
dc.typeMaster thesis


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