• Gibbs thermodynamics and surface properties at the nanoscale 

      de Miguel, Rodrigo; Rubi, J. Miguel (Peer reviewed; Journal article, 2021)
      Gibbs’s classical thermodynamic framework approximates systems as infinitely large phases separated by infinitely thin surfaces. The range of validity of this classical framework comes naturally under scrutiny as we become ...
    • Strong Coupling and Nonextensive Thermodynamics 

      de Miguel, Rodrigo; Rubi, Capaceti Jose Miguel (Peer reviewed; Journal article, 2020)
      We propose a Hamiltonian-based approach to the nonextensive thermodynamics of small systems, where 'small' is a relative term comparing the size of the system to the size of the effective interaction region around it. We ...