Blar i Institutt for materialteknologi på tidsskrift "Journal of Chemical Physics"
Viser treff 1-6 av 6
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Equation of state for confined fluids
(Peer reviewed; Journal article, 2022)Fluids confined in small volumes behave differently than fluids in bulk systems. For bulk systems, a compact summary of the system's thermodynamic properties is provided by equations of state. However, there is currently ... -
Kirkwood–Buff integrals: From fluctuations in finite volumes to the thermodynamic limit
(Peer reviewed; Journal article, 2022)The Kirkwood–Buff theory is a cornerstone of the statistical mechanics of liquids and solutions. It relates volume integrals over the radial distribution function, so-called Kirkwood–Buff integrals (KBIs), to particle ... -
Small Size Effects in Open and Closed Systems: What Can We Learn from Ideal Gases about Systems with Interacting Particles?
(Peer reviewed; Journal article, 2021)Small systems have higher surface area-to-volume ratios than macroscopic systems. The thermodynamics of small systems therefore deviates from the description of classical thermodynamics. One consequence of this is that ... -
Superoxide intermediate in the oxygen reduction on a zinc hydroxide model corrosion product
(Peer reviewed; Journal article, 2022)The inhibition of the electrochemical oxygen reduction reaction (ORR) by zinc corrosion products plays an important role in the corrosion protection of galvanized steel. Hence, the electrocatalytic mechanism of the ORR on ... -
Transport coefficients for ion and solvent coupling. The case of the lithium-ion battery electrolyte
(Peer reviewed; Journal article, 2023)Transport properties are essential for the understanding and modeling of electrochemical cells, in particular complex systems like lithium-ion batteries. In this study, we demonstrate how a certain degree of freedom in the ... -
Vibrational spectroscopic study of pH dependent solvation at an Ge(100)-water interface during an electrode potential triggered surface termination transition.
(Journal article; Peer reviewed, 2018)The charge-dependent structure of interfacial water at the n-Ge(100)-aqueous perchlorate interface was studied by controlling the electrode potential. Specifically, a joint attenuated total reflection infrared spectroscopy ...