Browsing NTNU Open by Author "Vullum-Bruer, Fride"
Now showing items 1-20 of 28
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3D aligned-carbon-nanotubes@Li2FeSiO4 arrays as high rate capability cathodes for Li-ion batteries
Zhou, Haitao; Lou, Fengliu; Vullum, Per Erik; Einarsrud, Mari-Ann; Chen, De; Vullum-Bruer, Fride (Journal article; Peer reviewed, 2013-09-27)3D aligned-carbon-nanotubes (ACNTs)@Li2FeSiO4 nanocomposite arrays on Al foil were developed as cathode materials for Li-ion batteries. The ACNTs were grown directly on an Al foil by a chemical vapor deposition method to ... -
A van der Waals Density Functional Study of MoO3 and Its Oxygen Vacancies
Inzani, Katherine; Grande, Tor; Vullum-Bruer, Fride; Selbach, Sverre Magnus (Journal article; Peer reviewed, 2016)The electronic structure of layered molybdenum trioxide MoO3 is highly sensitive to changes in oxygen stoichiometry as Mo6+ has an empty 4d shell. Applications of MoO3 are responsive to small changes in vacancy concentration, ... -
Alternative Methods for Curing of TCO Thin Films
Haugesten, Lise Helmine (Master thesis, 2014)Transparent conducting oxides have a unique combination of properties as they are both optical transparent in the visible region of the electromagnetic spectrum, and obtain a near-metallic conductivity. This makes them ... -
Are MXenes Suitable as Cathode Material for Rechargeable Mg Batteries?
Kaland, Henning; Hadler-Jacobsen, Jacob; Fagerli, Frode Håskjold; Wagner, Nils Peter; Wang, Zhaohui; Selbach, Sverre Magnus; Vullum-Bruer, Fride; Wiik, Kjell; Schnell, Sondre Kvalvåg (Peer reviewed; Journal article, 2020)MXenes, a type of two-dimensional transition metal carbide/nitride, have received significant attention for electrochemical storage applications. With substantial capacities predicted for Mg ions, MXenes have been considered ... -
Comparing electrochemical perormance of transition metal silicate cathodes and chevrel phase Mo6S8 in the analogous rechargeable Mg-ion battery system
Chen, Xinzhi; Bleken, Francesca Lønstad; Løvvik, Ole Martin; Vullum-Bruer, Fride (Journal article; Peer reviewed, 2016)Polyanion based silicate materials, MgMSiO4 (M = Fe, Mn, Co), previously reported to be promising cathode materials for Mg-ion batteries, have been re-examined. Both the sol-gel and molten salt methods are employed to ... -
Edge/basal/defect ratios in graphite and their influence on the thermal stability of lithium ion batteries
Foss, Carl Erik Lie; Svensson, Ann Mari; Sunde, Svein; Vullum-Bruer, Fride (Journal article, 2016)Raw graphite can be processed industrially in large quanta but for the graphite to be useful in lithium ion batteries (LIB's) certain parameters needs to be optimized. Some key parameters are graphite morphology, active ... -
Effect of carbon content and annealing atmosphere on phase purity and morphology of Li2MnSiO4 synthesized by a PVA assisted sol–gel method
Wagner, Nils Peter; Svensson, Ann Mari; Vullum-Bruer, Fride (Journal article; Peer reviewed, 2015)Lithium transition metal orthosilicates of the general formula Li2MSiO4 have gained great interest as potential positive electrode material for Li-ion batteries. This study reports the dependence of phase purity and ... -
Electrochemical impedance spectroscopy of a porous graphite electrode used for Li-ion batteries with EC/PC based electrolytes
Foss, Carl Erik Lie; Svensson, Ann Mari; Sunde, Svein; Vullum-Bruer, Fride (Journal article; Peer reviewed, 2012)Electrochemical impedance spectroscopy has been employed to investigate different electrolyte compositions used for lithium-ion batteries. Diffusion coefficients in ethylene carbonate (EC) was estimated to be in order of ... -
Electronic properties of reduced molybdenum oxides
Inzani, Katherine; Nematollahi, Mohammadreza; Vullum-Bruer, Fride; Grande, Tor; Reenaas, Turid Worren; Selbach, Sverre Magnus (Journal article; Peer reviewed, 2017)The electronic properties of MoO3 and reduced molybdenum oxide phases are studied by density functional theory (DFT) alongside characterization of mixed phase MoOx films. Molybdenum oxide is utilized in compositions ranging ... -
Fe and V substituted Li2MnSiO4/C As Potential Cathode Material for Li-Ion Batteries
Wagner, Nils Peter; Dalod, Antoine Robert Marie; Svensson, Ann Mari; Vullum-Bruer, Fride (Journal article; Peer reviewed, 2015)Lithium transition-metal silicate materials are promising candidates for next generation Li-ion batteries since they allow Li extraction/insertion beyond one Li ion per formula unit. They consist of cheap, non-toxic and ... -
Flame-made Lithium Transition Metal Orthosilicates
Wagner, Nils Peter; Svensson, Ann Mari; Vullum-Bruer, Fride (Journal article; Peer reviewed, 2016)Li2MSiO4 (M = Fe, Mn, Co) compounds have since their discovery gained increased attention as alternative, inexpensive and inherently safe positive electrodes for Li-ion batteries. To meet the required performance for an ... -
High capacity Mg batteries based on surface-controlled electrochemical reactions
Wang, Lu; Vullum, Per Erik; Asheim, Karina; Wang, Xuehang; Svensson, Ann Mari; Vullum-Bruer, Fride (Journal article; Peer reviewed, 2018)Mg batteries are one of several new battery technologies expected to partially substitute lithium-based batteries in the future due to the lower cost and higher safety. However, the development of Mg batteries has been ... -
High capacity nanostructured Li2FexSiO4/C with Fe hyperstoichiometry for Li-ion batteries
Zhou, Haitao; Einarsrud, Mari-Ann; Vullum-Bruer, Fride (Journal article; Peer reviewed, 2013-02-17)Li2FeSiO4-based materials have attracted a great deal of interest as cathodes for lithium ion batteries for its excellent thermal stability and good cycling ability. Nanoporous Li2FeSiO4/C composites with varying Fe ... -
High interfacial charge storage capability of carbonaceous cathodes for Mg batteries
Wang, Lu; Jiang, Bo; Vullum, Per Erik; Svensson, Ann Mari; Erbe, Andreas; Selbach, Sverre Magnus; Xu, Huailiang; Vullum-Bruer, Fride (Journal article; Peer reviewed, 2018)A rechargeable Mg battery where the capacity mainly originates from reversible reactions occurring at the electrode/electrolyte interface efficiently avoids the challenge of sluggish Mg intercalation encountered in ... -
In situ X-ray diffraction and electrochemical impedance spectroscopy of a nanoporous Li2FeSiO4/C cathode during the initial charge/discharge cycle of a Li-ion battery
Zhou, Haitao; Einarsrud, Mari-Ann; Vullum-Bruer, Fride (Journal article; Peer reviewed, 2013)Understanding of the structural evolution of the cathode during the charge/discharge processes is crucial to describe the Li insertion/de-insertion mechanisms in a Li-ion battery. An in situ XRD cell has been specially ... -
Inside the electrode: Looking at cycling products in Li/O2 batteries
Augustin, Matthias; Vullum, Per Erik; Vullum-Bruer, Fride; Svensson, Ann Mari (Journal article; Peer reviewed, 2019)This work investigates the impact of electrochemical reactions and products on discharge capacity and cycling stability with electrolytes based on two common solvents – tetraethylene glycol dimethyl ether (TEGDME) and ... -
Liquid feed flame spray pyrolysis as alternative synthesis for electrochemically active nanosized Li2MnSiO4
Wagner, Nils Peter; Svensson, Ann Mari; Vullum-Bruer, Fride (Journal article; Peer reviewed, 2016)A novel liquid-feed flame spray pyrolysis synthesis with reducing post-heat treatment yielding highly phase pure nano-sized and carbon-coated Li2MnSiO4 is reported. In contrast to most reported Li2MnSiO4 synthesis routes, ... -
Mn3O4 and Carbon-Based Cathode Materials for Magnesium Batteries
Wang, Lu (Doctoral theses at NTNU;2017:245, Doctoral thesis, 2017) -
On Vanadium Substitution in Li2MnSiO4/C as Positive Electrode for Li-ion Batteries
Wagner, Nils Peter; Vullum, Per Erik; Nord, Magnus Kristofer; Svensson, Ann Mari; Vullum-Bruer, Fride (Journal article; Peer reviewed, 2016)Vanadium substitution is an interesting approach to manipulate the properties of the poor electronic and ionic conducting lithium transition metal orthosilicates. Especially, if incorporated on the Si site, it could alter ... -
Performance and failure analysis of full cell lithium ion battery with LiNi0.8Co0.15Al0.05O2 and silicon electrodes
Wagner, Nils Peter; Asheim, Karina; Vullum-Bruer, Fride; Svensson, Ann Mari (Journal article; Peer reviewed, 2019)The influence of the lithium inventory on the performance and degradation mechanism of NCA||Si cells operating at a third of the theoretical silicon capacity is analysed. The lithium inventory was increased by electrochemical ...