Browsing NTNU Open by Author "Holta, Ann Christin Reiersølmoen"
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Au(III) complexes with tetradentate-cyclam-based ligands
Holta, Ann Christin Reiersølmoen; Solvi, Thomas Nordbø; Fiksdahl, Anne (Peer reviewed; Journal article, 2021)Chiral cyclam (1,4,8,11-tetraazacyclotetradecane) derivatives were synthesized stepwise from chiral mono-Boc-1,2-diamines and (dialkyl)malonyl dichloride via open diamide-bis(N-Boc-amino) intermediates (65–91%). Deprotection ... -
Catalytic Activity of trans-Bis(pyridine)gold Complexes
Holta, Ann Christin Reiersølmoen; Csokas, Daniel; Øien-Ødegaard, Sigurd; Vanderkooy, Alan; Gupta, Arvind Kumar; Carlsson, Anna-Carin C.; Orthaber, Andreas; Fiksdahl, Anne; Pàpai, Imre; Erdélyi, Máté (Peer reviewed; Journal article, 2020)Gold catalysis has become one of the fastest growing fields in chemistry, providing new organic transformations and offering excellent chemoselectivities under mild reaction conditions. Methodological developments have ... -
Symmetry of three-center, four-electron bonds
Holta, Ann Christin Reiersølmoen; Battaglia, Stefano; Øien-Ødegaard, Sigurd; Gupta, Arvind Kumar; Fiksdahl, Anne; Lindh, Roland; Erdélyi, Máté (Peer reviewed; Journal article, 2020)Three-center, four-electron bonds provide unusually strong interactions; however, their nature remains ununderstood. Investigations of the strength, symmetry and the covalent versus electrostatic character of three-center ... -
Tunable Gold-catalyzed Reactions of Propargyl Alcohols and Aryl Nucleophiles
Jonsson, Helgi Freyr; Solvi, Thomas Nordbø; Lomeland, Sondre; Holta, Ann Christin Reiersølmoen; Fiksdahl, Anne (Peer reviewed; Journal article, 2022)Gold-catalyzed transformations of 1,3-diarylpropargyl alcohols and various aryl nucleophiles were studied. Selective tunable synthetic methods were developed for 1,1,3-triarylallenes, diaryl-indenes and tetraaryl-allyl ...